• ossila材料NPNPB

    CAS Number 936355-01-0

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    产品详情

    NPNPB, full name N,N'-diphenyl-N,N'-di-[4-(N,N-diphenyl-amino)phenyl]benzidine, is one of the family members of triarylamines. NPNPB is electron rich and can be used as an electron-transport layer material for OLEDs and perovskite solar cells. Due to its electron-donating nature, NPNPB is also used together with electron acceptors (such as PO-T2T) to form exciplexes in highly-efficient thermally activated delayed fluorescence OLEDs.

    NPNPB is also introduced into the interface between ITO and NPB as a buffer layer. This works to smooth the ITO surface and lower the barrier to hole-charge injection.

    General Information


    CAS number 936355-01-0
    Full name N,N'-diphenyl-N,N'-di-[4-(N,N-diphenyl-amino)phenyl]benzidine
    Chemical formula C60H46N4
    Molecular weight 823.03 g/mol
    Absorption λmax 324 nm in THF
    Fluorescence λem 450 nm in THF
    HOMO/LUMO HOMO = 5.1 eV, LUMO = 3.0 eV [1]
    Synonyms N,N'-Bis[4-(diphenylamino)phenyl]-N,N'-diphenyl-3,3'-biphenyldiamine
    Classification / Family Triarylamines Organic electronics, Hole-transport layer materials (HTL), Hole-injection layer materials (HIL), TADF materials, Sublimed materials.

    Product Details


    Purity Sublimed: > 99% (HPLC)
    Melting point TGA: >370 °C (0.5% weight loss)
    Appearance Yellow powder/crystals

    *Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials.

    Chemical Structure


    npnpb, 936355-01-0
    Chemical structure of N,N'-diphenyl-N,N'-di-[4-(N,N-diphenyl-amino)phenyl]benzidine (NPNPB), CAS 936355-01-0

    Device Structure(s)


    Device structure ITO/NPNPB (60 nm)/NPB (10 nm)/TCTA (10 nm)/BIQMCz*: Ir(piq)3 (4 wt%) (30 nm)/BAlq (30 nm)/LiF (1 nm)/Al (100 nm) [1]
    Colour Red red light emitting device
    Max. Power Efficiency 26.2 lm W-1
    Max. EQE 23.3%
    Max. Current Efficiency 27.1 cd/A
    Device structure ITO/NPNPB (60 nm)/NPB (10 nm)/DMPPP:2 wt% 1bb* (30 nm)/BAlq (20 nm)/LiF (1 nm)/Al [2]
    Colour Blue blue light emitting device
    Max. Power Efficiency 4.23 lm W-1
    Max. EQE 5.2%
    Max. Current Efficiency 5.38 cd/A
    Device structure ITO/NPNPB (60 nm)/NPB (10 nm)/DMPPP:2 wt% 2bb* (30 nm)/BAlq (20 nm)/LiF (1 nm)/Al [2]
    Colour Blue blue light emitting device
    Max. Power Efficiency 4.23 lm W-1
    Max. EQE 4.72%
    Max. Current Efficiency 5.87 cd/A
    Device structure ITO/NPNPB (60 nm)/NPB (10 nm)/DMPPP:2 wt% 2bb* (30 nm)/BAlq (20 nm)/LiF (1 nm)/Al [2]
    Colour Blue blue light emitting device
    Max. Power Efficiency 4.23 lm W-1
    Max. EQE 4.72%
    Max. Current Efficiency 5.87 cd/A
    Device structure ITO/NPNPB: 10% MoO3 (5 nm)/NPNPB (80 nm)/NPB (10 nm)/DMPPP: 5% TSTA* (25 nm)/BAlq2 (20 nm)/LiF (1 nm)/Al (100 nm) [3]
    Colour Blue blue light emitting device
    Max. Power Efficiency 5.7 lm W-1
    Max. EQE 10.2%
    Max. Current Efficiency 12.3 cd/A
    Device structure ITO/NPNPB: 10% MoO3 (5 nm)/NPNPB (80 nm)/NPB (10 nm)/DMPPP: 5% TSMA* (25 nm)/BAlq2 (20 nm)/LiF (1 nm)/Al (100 nm) [3]
    Colour Blue blue light emitting device
    Max. Power Efficiency 8.7 lm W-1
    Max. EQE 8.9%
    Max. Current Efficiency 10.3 cd/A
    Device structure ITO/NPNPB (50 nm)/NPB (10 nm)/DMPPP: PPIE (5 wt%) (25 nm)/BAlq (20 nm)/LiF (1 nm)/Al (100 nm) [4]
    Colour Blue blue light emitting device
    Max. Power Efficiency 4.8 lm W-1
    Max. EQE 8.1%
    Max. Current Efficiency 10.0 cd/A

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